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raffaellopalandri · 8 months
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Action for Happiness Calendar - September 2023
Here you are the Action for Happiness calendar for September 2023: Action for Happiness Calendar September 2023 This month’s theme is Self-Care. Self-care is important because it helps you maintain your physical, mental, and emotional health. When you take care of yourself, you are better able to cope with stress, manage your emotions, and have more energy. Self-care can also help you improve…
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intensethought · 6 months
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In this video, we talk about how to interact with energy and strengthen the experiences you have with other people. When you are interacting with people, your energy level is incredibly important. Your energy attracts people to you, enhances the experience for both of you, motivates others to do things and protects you from loss, risk and danger. If you are weak in this area, it affects everything that you do.
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willowrogers · 7 months
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Granola Bar - Sharon's No-Bake Granola Bars These delicious, energizing no-bake granola bars will sell out as quickly as you can make them.
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fixionaria · 9 months
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Sharon's No-Bake Granola Bars These yummy, energizing no-bake granola bars are going to disappear as fast as you can make them.
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wishikawa · 9 months
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The first reaction kinetics in the world with regard to indoaniline dye forming(9).
1H-pyrazolo[5,1-C] [1,2,4] triazole (hereinafter referred to as "pyrazolo-triazole")
Pyrazolo-triazole is a coupler.
Due to the variations of the substituent on the 4 equivalent pyrazolo-triazolic structure of mother nucleus, there exist hight energy level of the coupler's HOMO(H) and low one(L), even within the appropriate range.
Due to the introduction of halogen atom into the carbon atom on the active point of those couplers, the energy level of coupler's (Next)HOMO decrease.
(When a halogen atom is introduced into the carbon at the coupler's active point, it is necessary to concider not only the energy level of HOMO but also the energy level of NextHOMO.)
In the case of (H), the energy level of halogenized 2-equivalent coupler's (Next)HOMO remains within an appropriate range and its coupler shows sufficient coupling reactivity. In the case of (L), the energy level of halogenized 2-equivalent coupler's (Next)HOMO goes down over an appropriate range and its coupler shows unsufficient coupling reactivity.
When the cyan dye produced from pyrazolotriazole(H) is compared to the cyan dye produced from pyrazolotriazole(L), on the triazole side it becomes a shortened wave and appears as a shoulder of the absorption waveform. (See "The first reaction kinetics in the world with regard to indoaniline dye forming (6)")
phenolic coupler and 2-carbamoylnaphtholic coupler
Even when the conventional 4-equivalent phenolic coupler is (H) and the 4-equivalent 2-carbamoylnaphtholic coupler is (L), the same phenomenon has occured.
Both (H) and (L) show sufficient coupling reactivity. The halogenized 2-equivalent couple(H) shows sufficient coupling reactivity. The halogenized 2-equivalent couple(L) shows unsufficient coupling reactivity.
Therefor, the phenomenon can be explained based on the same logic described in this blog.
azomethine dye forming reaction
In the case of azomethine dye forming reaction, the relationship between a 4-equivalent coupler and 2-equivalent coupler in the coupling reaction's rate, the relationship between a 4-equivalent coupler and 2-equivalent coupler in the dye forming reaction's rate, and the relationship between the coupling reaction's rate and the dye forming rate also can be explained based on the logic described in this blog.
HOMO : Highest Occupied Molecular Orbital LUMO : Lowest Unoccupied Molecular Orbital
conclusion
All the facts described in this blog post are well known or publicly known but the reaction kinetics itself which is as the title of this blog post.
References: The following publications are references for further details. The Theory of the Photographic Process FOURTH EDITION Edited by T.H.James MACMILLAN PUBLISHING CO., INC. Molecular Orbital Method Written by Minoru Hirota SHOKABO Co., Ltd. Frontier Orbitals and Organic Chemical Reactions Written by Ian Fleming Supervised by Kennichi Fukui Translated by Takeuchi Yoshito, Tomoda Syuuji KODANSHA SCIENTIFIC Co., Ltd. The Seminar of Organic Chemical Reactions Witten by Naoki Inamoto,Kinya Akiba,Renji Okazaki NANKODO Co., Ltd. Physical Chemistry Written by Raymond Chang Translated by Iwasawa Yasuhiro, Kitagawa Teizou, Hamaguchi Hiroo TOKYOKAGAKUDOJIN Co., Ltd. KONICA MINORUTA TECHNOLOGY REPORT VOL2 (2005) https://research.konicaminolta.com/jp/pdf/technology_report/2005/pdf/treatise_014.pdf
Klopman/ Salem Equation http://ramsey1.chem.uic.edu/chem533/page5/page10/files/Klopman-Salem%20Equation.pdf
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fearandloathingblog · 10 months
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Sharon's No-Bake Granola Bars These delicious, energizing no-bake granola bars will sell out as quickly as you can make them.
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fyi-iyanni · 4 months
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When you that girl 💕✨
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foreverrryourssss · 2 months
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chichimodele · 6 months
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Dark Feminine
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clairertemple · 1 year
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Sharon's No-Bake Granola Bars - Granola Bar These delicious, energizing no-bake granola bars will sell out as quickly as you can make them.
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elonomhblog · 1 month
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how to stay motivated long-term
trust, me i know that long-term motivation and consistency is hard. long-term motivation might be difficult to maintain, but there are effective techniques to help you stay focused and determined. whether you're seeking personal ambitions, academic achievements, or professional success, here are some strategies to help encourage motivation:
understand the reason behind your goal ☆ does your goal contribute to personal growth or meaningful relationships? ☆ how does your goal impact others? ☆ is your goal meaningful to you? if your goal lacks meaning, it may be hard to maintain motivation.
positive and negative motivation motivation can come from different places ☆ positive motivation: the desire to experience pleasure ☆ negative motivation: the desire to avoid something (an outcome) both types of motivation have their place, so learn to recognise what type fits in where. (post on this coming soon)
set up systems use your initial motivation to set up structures: ☆ create routines, systems and habits that help you towards your goal even when your motivation fluctuates ☆ when your emotions wane, rely on these systems and disciplines to maintain momentum
break down goals ☆ tackle one goal at a time to avoid feeling overwhelmed ☆ set achievable milestones and celebrate each step forward ☆ keep the momentum going by focusing on manageable tasks
validate good work ☆ give yourself a little reward, or thank yourself, for completing hard tasks ☆ this reinforces motivation and encourages effort
remember--motivation isn't in a constant state, it ebbs and flows. these small tips will help to stay motivated. i'm going to provide more information in upcoming posts, and i will link them here once they are published.
luck on your journey ❤️
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days-may · 1 month
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I wanna see what happens if I don't give up
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theambitiouswoman · 7 months
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How to Be The ✨Main Character✨ of Your Life 👑
Being the main character of your life means taking charge of your own narrative, making intentional choices, and living authentically. This doesn't mean life will be perfect. It means you're actively participating in your journey, making choices that align with your values, and striving to live a fulfilling life.
Understand yourself. Your desires, strengths, weaknesses, and emotions. What you like and do not like. Reflect on your actions and decisions regularly.
Figure out, decide and commit to the life you want.Both short term and long term. Break these goals down into small steps.
Take action. Don't wait for things to happen; make them happen.
Every main character faces obstacles. They build you. They show you, and others, how bad you want it. Instead of avoiding challenges, face them head-on. They're opportunities for growth.
Physical, emotional, and mental well-being are crucial. Regular exercise, a balanced diet, meditation, and adequate sleep can make a huge difference. How you treat yourself is how much you do or do not love yourself.
Surround yourself with positive influences and people who uplift you. Limit exposure to negative media or toxic individuals.
The world is full of knowledge. Always be curious. Read books and take courses. Always learn.
Connect deeply with others. Genuine relationships add richness to life.
Be true to yourself. Don't live to meet others' expectations. Celebrate your uniqueness.
Regularly acknowledge and appreciate the good in your life. There is always something to be grateful for. It shifts your focus from what's lacking to what's abundant. How you look at life is what you will attract.
Find balance in work, relationships, and personal time. Create a life that is fulfilling. You are not just one aspect of your life.
Imagine yourself succeeding and achieving your goals. This positive visualization can be a powerful motivator. Live your life as if it is already done.
Life will have its ups and downs. Resilience is the ability to bounce back from setbacks and keep moving forward.
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wishikawa · 9 months
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The first reaction kinetics in the world with regard to indoaniline dye forming (8).
The 2-carbamoylnaphthol with active point substituted.
ⅰ) Due to the introduction of halogen atom into the carbon atom of 2-carbamoylnaphthol's active point, the energy level of this 2-equivalnt 2-carbamoylnaphthol's (Next)HOMO(E*nr) goes down the less than the appropriate range to make the coupling rate slow.
(When a halogen atom is introduced into the carbon at the coupler's active point, it is necessary to concider not only the energy level of HOMO but also the energy level of NextHOMO.)
It correspond to the case of k'>>k, mentioned in "The first reaction kinetics in the world with regard to indoaniline dye forming (4)", since the indoaniline dye forming rate from this 2-equivalnt 2-carbamoylnaphthol goes down, the density of dye is the less than the enough one.
ⅱ)Due to the introduction of substituent through the oxygen atom into the carbon atom of 2-carbamoylnaphthol's active point, the energy level of this 2-equivalnt 2-carbamoylnaphthol's HOMO(E*nr) goes up within the appropriate range.
It does not impair the rate of couplling reaction but it does not reach to a point that acceralate the one, due to the incapability to avoid decrease the molecular orbital coefficient of carbon atom on this 2-equivalnt 2-carbamoylnaphthol's active point.
Still, the magical world goes around!
 ⊿Etotal=-qr・qs / Rrs +2(Cmrr・Cnss・⊿β)² /(E*nr-E*ms)  (the second term)  (the third term)  (the first term is omitted)  (coulomb term)      (electron transfer interaction term)
where
E*nr is the energy level of the coupler anion's HOMO, E*ms is the energy level of quinonediimine's LUMO, Cmrr is the molecular orbital coefficient of carbon atom on the coupler's(HOMO's) active point , Cnss is the molecular orbital coefficient of nitrogen atom on the quinonediimine's(LUMO's) reaction point , Δβ is the stabilization energy due to the formation of CN bond.  It's equivalent to the amount of change in the resonance integral.
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gent-illmatic · 5 months
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2024 IS NOT FOR "PLAY PLAY" .
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digitalgirlguide · 3 months
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BECOMING THE WOMAN YOU WANT
Imagine the woman you want to become. Envision her embracing a lifestyle woven with healthy habits that radiate positivity and well-being. Picture her waking up early, greeting the day with gratitude, and setting intentions that shape her mindset for success.
In her daily routine, she prioritizes self-care—nourishing her body with wholesome meals, staying hydrated, and indulging in regular exercise that she genuinely enjoys. Whether it's a morning yoga session, an evening run, or a dance class, physical activity is not a chore but a celebration of what her body can achieve.
This woman values the power of mindfulness. Picture her taking moments throughout the day to breathe deeply, practice meditation, or simply appreciate the present. It's in these mindful pauses that she finds clarity, resilience, and a profound connection with herself.
As she moves through her day, healthy habits extend into her work life. This woman is organized and efficient, using time management techniques to tackle tasks without feeling overwhelmed. Regular breaks and moments of reflection help her maintain focus and creativity.
Evenings are a sanctuary for winding down. She cherishes a good night's sleep, prioritizing rest as a cornerstone of her well-being. Unplugging from screens, engaging in calming activities, and maintaining a consistent sleep schedule contribute to the rejuvenation her body and mind need.
Remember, becoming her doesn't happen overnight. It's a gradual process, a collection of intentional choices and persistent efforts. Start incorporating these healthy habits, step by step, and watch as you evolve into the empowered, balanced woman you aspire to be. 🌿💪🌺🌟
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