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#p333
feralchaton · 10 months
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Louise Glück | Poems 1962 - 2012 | excerpt from Parable Of The Dove | Meadowlands
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the-fiction-witch · 3 months
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I dare you... P3
Media The Artful Dodger
Character Jack Dawkins
Couple Jack X Reader
Rating Smut
I dare you P333!!!!! 🙏🏼🙏🏼🙏🏼
Part 3 please 🥺🙏
WOW THATS CRAZY! Part 3 plzzzz
OMG I REALLY WANT TO SEE what happens next PLEASE PART 3333333
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"One end to the other?" Jack asked,
"Yep." I nodded,
"Naked?"
"Yes, Jack."
"...How naked?"
"As naked as you were born." 
"Not on your life."
"Don't do it you have to kiss Prof."
"...How much do I have to kiss him?"
"On the lips for at least a minute," 
"...... from where in the hospital?"
"Here."
"To?"
"The morgue."
The look on his face was deep contemplation, neither was a good option. 
"What if someone sees me!"
"well best be sneaky then. No one is about and I'll let you off having to go through the ward."
"But I have to go past it to get the morgue."
"Yeah, you do."
"But if I don't... Ughr- I have to kiss prof." 
"Yep. On the lips and I'll be watching to make sure you do it." 
He thought for a moment really weighing his options out when he stood up in the centre of the theatre, "From here to the morgue?" He clarified taking his tie off, 
"Yep," I giggled,
he began to undo his waistcoat "I hate you." He said, slipping it off, then peeling his suspenders off his shoulders I couldn't help but watch him, "I hate your evil little brain," He said as he undid his trousers pushing them off, "I hate everything about this situation." He said taking his shirt off and dumping his clothes in a pile on the table, 
"As naked as you were born Doctor Dawkins," I giggled looking at his white cotton underwear, 
"I hate everything about you right now."
"I know," I giggled, 
He rolled his eyes and pulled his cotton undergarments off, leaving him completely exposed, using his hands to conceal himself, 
"Go on begin your walk," I smirked, 
"This is the worst dare of my life." I sighed, 
He slowly creeped out of the theatre doing his best to keep covered, but also keep his head constantly looking in every possible direction to make sure he wasn't seen by anyone. I smirked crossing my arms over my chest and following behind him but far enough I couldn't protect him, I couldn't stop my giggles watching him try to keep himself concealed given he was still hard, he snuck himself through the entryway slowly and carefully, heading slowly through the halls. Hummm this could be more interesting, I slapped his pale butt making him jump.
"Ahhh! Y/n!" He complained, 
"You can't use your hands anymore."
"That was not part of the dare."
"Yes, but I think you are cheating," 
"cheating! you really want me to walk through this hospital with my bloody cock out?"
"Yes."
"Fuck it. No, I'd rather kiss Prof. I'll kiss Prof and sneed if I can just keep my hands here y/n,"
"If you make it to the morgue without using your hands you'll get a reward," I smirked starting to walk to the morgue. 
"A reward?"
"Mhm..."
"What sort of reward?"
"A reward that involves my mouth."
"..you- your mouth?" he smirked, "fine." He sighed not using his hands to conceal himself even if he desperately wanted to, so we continued to sneak through the hospital even if a passing nurse headed for the ward did make Jack literally leap into the store room with speed I had never seen before, 
"Evening Miss Y/l/n" she nodded to me,
"Evening Miss Smith," I nodded back as she walked past,
"Is she gone?" Jack gulped poking his head out,
"Yes, you're safe."
"...I don't know if I trust you." he complained but he saw the morgue stairwell so basically bolted for it and down the stairs I happily followed him finally arriving in the morgue where I shut the doors. "yes! I did it! Now where is my reward!" he smirked, 
"Alright you win Jack, you get your reward," I smirked, "You want it now?" 
"Yes!" He smirked leaning his elbows against the morgue table, "I did it, so I need my reward y/n," He slyly and invitingly smiled, 
"Alright," I moved to wrap my arms around his neck and to give him some sweet kisses which he happily returned until I pulled back and kissed down his neck and down his chest until I met his now stiff erection I kissed his hips and down his V before slowly pressing gentle kisses down his shaft, he groaned wrapping his fingers into my hair, once I tested him a little I took him into my mouth fully and gently sucked bobbing my head back and forth down his shaft often licking and swirling my tongue around his head, at times gracing my teeth against the underside of his shaft, he reacted well to my work groaning and moaning above me his hand guiding my head even if I often ignored his guiding just to tease him even more, winding him tighter and tighter and tighter until he grabbed my head pulling me to deep throat him as he moaned loudly his hips bucking into my mouth uncontrollably as he buried himself in my mouth coating my tongue, his body collapsed against the table his head thrown back.
I giggled and pulled back swallowing and licking him clean as well as my lips before I returned to my feet and fixed my hair, "Pleased with your reward Doctor Dawkins?"
"Very pleased," He smirked, "I'd kiss you but... you know,"
"Yeah, doesn't seem like the best idea." I laughed, "So a good reward?"
"Very good, I'd almost be willing to do it again if that's the reward I get,"
"Good" I smirked, "Cause you forget something."
"What did I forget darling?"
"Where's your clothes?"
He stopped and looked around, "Ohh my god- my clothes are still in the theatre."
"Yes, they are,"
"Why didn't you bring them!"
"you didn't ask me to."
"Please go get them for me y/n."
"Nope"
"what!"
"No."
"Y/n!"
"I said no."
"Y/n! You're not serious! you're not going to make me walk all the way back!"
"Yes, I am."
"You... are an evil little thing." He complained,
"Come on then Jack off we go."
"I hate you." He glared as we had to do it all again, He bolted up the stairs and yet again I smiled following behind him watching as he snuck all the way he just came all the way back to the theatre where he immediately grabbed his clothes getting his pants on, "Ohh my god I am getting you back for this."
"Are you now?"
"I am." He smirked, "Truth or dare?"
"Dare."
"Hummm alright. I dare you to strip naked and go into every room in the hospital even the courtyard completely naked."
"Yeah?"
"Yeah."
"Or else what?"
"Or you have to go kiss Prof. On the lips."
I nodded and headed out the theatre, he quickly got dressed and followed me as I went down to prof's office where he stood very drunk trying to make his way to bed, "Professor?"
"Hummm? Dawkins... and... Maid... what is going on? we have an emergency?" he mumbled,
"No, you just need to get to bed," I told him as I headed over grabbed his face and kissed him, he tasted like whiskey and his beard was rough as I kissed him a few times before I pulled away letting him collapse drunk on the floor, I smirked turning to Jack and flipping my middle finger at him, "Get fucked Jack." I smirked, 
"Point taken." he nodded,
"I'm heading up to bed, but this was fun we'll have to play again sometime" I smiled giving Jack's cheek a kiss before I went up to bed. 
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brynberrycomic · 9 months
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p333
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kennak · 6 months
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平等とインクルージョンが必要だという主張を、遺伝的にはすべての人がみな同じだとか、遺伝的性質は人間の心理には影響を及ぼさないとかいう前提の上に打ち立てる必要はないのだ。修正されるべきは、人々がどんな遺伝的バリアントを受け継いでいるかによらず、この国の社会的・経済的生活にすべての人が十分に参加できるように社会を作り替えることに後ろ向きな、社会そのものなのである。(p333)
アンチ優生学の立場で、遺伝がもたらす人生への影響を「平等」の観点から考え直す──『遺伝と平等―人生の成り行きは変えられる―』 - 基本読書
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computer-cats · 1 year
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i need laik a reaaaally huge buff matesprit with something supurr wrong with him 2 rock my world but he’s too gross and pawthetic and scared 2 do anything by himsmelf. i want a matesprit who shakes and p333s his pants beclaws he has to go outside 2 get the mail and i want him to cry when he asks for no pickles
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chemwhat · 4 days
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L-Threonic acid magnesium salt CAS#: 778571-57-6
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IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product NameL-Threonic acid magnesium saltIUPAC Namemagnesium;(2R,3S)-2,3,4-trihydroxybutanoateMolecular StructureCAS Registry Number 778571-57-6MDL NumberMFCD16621117Synonyms3-Pyridinamin;3-Pyridinamine;3-Pyridinamine;pyridin-3-amine;T6NJ CZ;3- Aminopyridine;3-Amino-pyridine;3-pyridylamine;Amino-3 pyridine;m-778571-57-6Magnesium L-ThreonateL-Threonic acid magnesium saltMagnesium (2R,3S)-2,3,4-trihydroxybutanoateMagnesium L-threonate anhydrous1Y26ZZ0OTML-Threonic acid (magnesium)Magnesium bis2088918-94-7UNII-1Y26ZZ0OTMC8H14MgO10MFCD16621117BISmagnesiumDTXSID30670457AMY32635AKOS015896711Magnesium, bis((2R,3S)-2,3,4-trihydroxybutanoato-kappaO,kappaO')-, (T-4)-MAGNESIUM L-THREONATE DB-101157HY-134240CS-0140508magnesium;(2R,3S)-2,3,4-trihydroxybutanoateA839248Q6731374Magnesium L-threonate;Magnesium (2R,3S)-2,3,4-trihydroxybutanoateMagnesium (2R pound not3S)-2 pound not3 pound not4-trihydroxybutanoateMAGNESIUM, BIS((2R,3S)-2,3,4-TRIHYDROXYBUTANOATO-.KAPPA.O,.KAPPA.O')-, (T-4)-Molecular FormulaC8H14MgO10 Molecular Weight294.5InChIInChI=1S/2C4H8O5.Mg/c2*5-1-2(6)3(7)4(8)9;/h2*2-3,5-7H,1H2,(H,8,9);/q;;+2/p-2/t2*2-,3+;/m00./s1InChI KeyCUYKNJBYIJFRCU-UHFFFAOYVJOHOWNFPQSPP-BALCVSAKSA-L Isomeric SMILESC(((C(=O))O)O)O.C(((C(=O))O)O)O. Physical Data AppearanceWhite powder Spectra No data available Route of Synthesis (ROS) No data available Safety and Hazards Pictogram(s)SignalWarningGHS Hazard StatementsH317 (100%): May cause an allergic skin reaction H319 (100%): Causes serious eye irritation Precautionary Statement CodesP261, P264+P265, P272, P280, P302+P352, P305+P351+P338, P321, P333+P317, P337+P317, P362+P364, and P501(The corresponding statement to each P-code can be found at the GHS Classification page.) Other Data TransportationUnder room temperature away from lightUnder room temperature away from lightHS CodeStorageUnder the room temperature and away from lightShelf Life2 yearsMarket Price Use PatternL-Threonic acid magnesium salt CAS 778571-57-6 is a commonly used food additive with various applications in the industrial, agricultural, and feed industries. It serves as a plant nutrient supplement, providing magnesium for plant absorption, thereby promoting plant growth and development. It is also utilized as a food additive. Read the full article
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saffordscellar · 5 months
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Check out this listing I just added to my Poshmark closet: Aritzia Babaton Top M Long Sleeve Waffle Knit Oversized Drop Shoulder Lounge.
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swatechelectrica · 6 months
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In stock sell>> MICOM P122 AREVA/ALSTOM, MICPM P127 AREVA, MICOM P141 AREVA/ALSTOM, MICOM P142 AREVA /ALSTOM, MICOM P143 AREVA/ALSTOM, MICOM P220 AREVA, MICOM P225 AREVA, MICOM P332/P333 ALSTOM, MICOM P443 ALSTOM, MICOM P543 AREVA, MICOM P591 ALSTOM, MICOM P631/P632/P633 AREVA/ALSTOM, MICOM P742 ALSTOM, MICOM P841, MICOM P847 AREVA.
Original ALSTOM/AREVA - UK/Canada.
Mobile/WA: +62 812 2277-7236
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mmorgbuzz · 2 years
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Qualcomm atheros drivers xp
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#Qualcomm atheros drivers xp 64 Bit
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Qualcomm Atheros Wireless Network Adapter Windows Xp Starter Edition 64bit 20092 Qualcomm Atheros Wireless Network Adapter Windows Xp Starter Edition 64bit 81.1841.1 Panasonic CF-C1BEAADR, Compaq EV958AA-ABF SR1804FR FR620, Acer TravelMate 5740G, Toshiba Dynabook Qosmio D711/T3EB, Sony VGX-TP1V, NEC POWERMATE RD391161295, LG LW75-P333, HP HP Pavilion dv9500, NEC PC-MY26LEZ78, and more. Qualcomm Atheros Wireless Network Adapter Windows Xp Starter Edition 64bit 2382.10 Mustek KDZ68DBM, HP HP Compaq nc6320, Lenovo 2429B56, Itautec Infoway w7730, and more. Qualcomm Atheros Wireless Network Adapter Windows Xp Starter Edition 64bit N302.10 HP DY149A-ABU t540.uk, IBM ThinkCentre S50, Sony VPCCW21FD, LG RD410-L.ADA3E2, Compaq EV958AA-ABF SR1804FR FR620, HP F元08AA-ABD IQ512de, Compaq VS459AA-ABE CQ5211ES, Sony VPCEJ2S1R, NEC EASYNOTE P910401306, HP HP Compaq 2710p, HP WC694AA-UUG HPE-110be, BenQ Joybook P51, ASUS ET2400IGTS-H61, and more. Qualcomm Atheros Wireless Network Adapter Windows Xp Starter Edition 64bit Z4302.16 Qualcomm Atheros Wireless Network Adapter Windows Xp Starter Edition 64bit 83226
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#Qualcomm atheros drivers xp 32 bit
Scan performed on, Computer: OEM By O.E.M - Windows 7 32 bit
#Qualcomm atheros drivers xp serial
Nokia Nokia Asha 311 USB Serial Port (COM5) Lenovo Lenovo 800dpi ScrollPoint Optical (HID) Point Grey Research Texas Instruments 1394 OHCI Compliant Host Controller Intel(R) 6300ESB Ultra ATA Storage/SATA Controller - 25A3 Qualcomm Atheros Qualcomm Atheros AR9285 Wireless Network Adapter Intel Controller Universal Host USB Intel(R) 82801FB/FBM -265BĪdvanced Micro Devices AMD Radeon HD 6800 Series Intel(R) 82801FB/FBM SMBus Controller - 266A (Standard mouse types) HID-compliant mouseĬorrupted By Qualcomm Atheros Wireless Network Adapter Windows Xp Starter Edition 64bit Intel(R) 8 Series PCI Express Root Port #5 - 9C18 Outdated or Corrupted drivers: 7/19 Device/Driver
#Qualcomm atheros drivers xp 64 Bit
Scan performed on, Computer: HP KT362AA-ABU m9258.uk-a - Windows 7 64 bit
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recordsmmorg · 2 years
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Nvidia geforce 7600 drivers windows 10
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NVIDIA GEFORCE 7600 DRIVERS WINDOWS 10 INSTALL
NVIDIA GEFORCE 7600 DRIVERS WINDOWS 10 64 BIT
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NVIDIA GEFORCE 7600 DRIVERS WINDOWS 10 WINDOWS 7
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LG R470-K.AR85L, Panasonic CF-18KH2ZXBC, Toshiba Satellite P870, Compaq PN124AA-ABU SR1219UK GB440, and more. If youre having trouble with display after upgrading to Windows 10, Download Windows 10 Compatible Nvidia GeForce Graphics Card Driver and follow given. Sony VGN-SZ76GN_B, Packard Bell IMEDIA J4715 AIO, NEC PC-LL550KG1J, Toshiba Dynabook T552/36FWK, Sony VGN-FE21HR, HP KA770AA-ABU m9175.uk-a, NEC VERSAL2101 RND51047895, and more. Lenovo 3000 J115 Desktop, ASUS L8400F series Notebook PC, HP RQ407AAR-ABA a1748x, Compaq PS245AA-ABF SR1339FR FR510, ECS H57H-MUS, Fujitsu LifeBook A6210, HP HDX9300, Wortmann U14M, and more. HP PN176AA-ABN t770.no, Advent PQG9002, Acer Shangqi X4610, Acer Aspire 1420P, Panasonic CF-30CASCZBM, Sony VPCEG1S1R, NEC EASYNOTE PB47S00286, and more.
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Lenovo 6075Y74, Sony VGN-AW120D, Acer Veriton Z290G, NEC EASYNOTE P910401306, and more. Nvidia Geforce 7600 Gs Driver Downloads - GeForce Windows 10 Driver, NVIDIA Graphics Driver (Windows 7 64-bit / Windows 8 64-bit), NVIDIA Graphics Driver. Download drivers for nVidia GeForce 7600 GT video cards (Windows 7 圆4), or install DriverPack Solution software for automatic driver download and update. Gateway MX7337H, IBM 2530A56, SAMSUN P580, ECS SMACKER II-MS300, HP Presario R3200, Fujitsu FMVA42EWKS, HP P6-2370ef, Intel C16, HP HPE-367c, ICP / IEi IMBA-Q454, ADVANC Modelo_A, HP GQ538AA-ABD, and more.
NVIDIA GEFORCE 7600 DRIVERS WINDOWS 10 64 BIT
'Nvidia 307.68 driver' 32 bit (Win7) or 'Nvidia 307.83 driver' 64 bit (Win8) and will also allow Nvidia GeForce Experience to load and function of course with out some capabilities due to age of card. HP GQ498AAR-ABA m9047c, Acer Veriton M688G, Compaq DD373A-ABY 6650 DK110, IBM ThinkCentre A52, Lenovo ThinkPad Twist S230u, IBM IBM eServer x226-[8648W16, HP Presario 2500, HP GZ729AAR-ABA a6317c, Intel C16, and more. WINDOWS 10 - Nvidia GeForce Go 7600 - GO 7300 Ive installed Windows 10 on different types of systems with GO 7300 cards with these desktop drivers. Panasonic CF-SX2JE4DS, Sony VPCW126AG, HP HP Touchsmart 300-1120, HP Pavilion ze2000, IBM 6830TBG, HP D7219A-ABA 555Y, Sony SVS13125CHB, Sony VGN-SZ57SN_C, IBM 8184W3Z, Fujitsu FMVFE90DBY, and more. Intel(R) 82801EB Ultra ATA Storage Controllers - 24D1įujitsu PRIMERGY RX200 S6, LG LW75-P333, HP PW665AA-ACJ a815i, Lenovo ThinkPad X201 Tablet, Lenovo 6071W8L, Fujitsu FMVLX50LX, Sony VGN-SZ7RMN_B, NEC PC-MY26AEZR4, Sony VGN-A215M, Toshiba Dynabook EX/56LWH, and more.įujitsu CELSIUS R930, Sony VGC-JS52JB_S, ASUS ESC4000 G2 Series, Notebook MIM2280, and more. Intel Intel(r) AIM External TV Encoder Driver 1 NVIDIA Standard Dual Channel PCI IDE Controller Ce pilote prend également en charge la version beta du Kit de développement GameWorks VR pour la réalité virtuelle. Realtek Realtek RTL8723AE Wireless LAN 802.11n PCI-E NIC À l’occasion de la sortie anticipée de Ashes of the Singularity, ce nouveau pilote GeForce vous offrira une expérience optimale dans ce passionnant jeu de stratégie en temps réel. Realtek Realtek AC97 Audio for VIA (R) Audio Controller Intel(R) Dynamic Platform & Thermal Framework PCH Participant Driver Outdated or Corrupted drivers: 4/21 Device/Driver
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Scan performed on, Computer: BenQ Joybook S32 - Windows 7 32 bit Huawei Vodafone Mobile Broadband Secondary Port Modem (Huawei) (COM28) Intel Intel(r) AIM External Flat Panel Driver 7ĪTI RADEON X600 Series (Microsoft Corporation - WDDM) Intel(R) 82810 Graphics Controller (Microsoft Corporation) Intel Intel(r) AIM External Flat Panel Driver 5 Point Grey Research Texas Instruments OHCI Compliant IEEE 1394 Host Controller
NVIDIA GEFORCE 7600 DRIVERS WINDOWS 10 UPGRADE
Intel(R) 6 Series/C200 Series Chipset Family USB Enhanced Host Controller - 1C26īuffalo BUFFALO WLI-UC-GNM Wireless LAN Adapter I have just upgraded from Windows 8.1 to Windows 10 Pro 32 ENG-GB on a Toshiba Qosmio G 20 120 laptop with NVIDIA GeForce Go 6600 graphic card, but after the upgrade a Microsoft Basic Display Adapter driver has been installed (Driver version. Intel(R) 82801G (famiglia ICH7) PCI Express Root Port - 27D2 Outdated or Corrupted drivers: 5/19 Device/Driver Scan performed on, Computer: HP HP Pavilion dv6-6c73ca - Windows 7 64 bit
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mda20009assignment · 2 years
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Week 8: Body Modification
‘42% of surgeons report that their patients are seeking aesthetic surgery to improve their appearance on Instagram, Snapchat, Facebook, and other social media channels.’ (Dorfman et al, 2018, p333) That’s the kind of impact that social media is having on the average person and their appearance. When people see their favourite influencers looking amazing in every single thing they post on social media, they want to transform themselves to be like that person with the pretty face or the perfect body whether it be male or female.
This leads us to the trend of body modification via cosmetic surgery, a trend that’s designed to help people become, in their mind’s eye, the perfect version of themselves. Cosmetic, also known as plastic, surgery has become a way for everyday folk to look as perfect as the glossy, airbrushed versions of the influencers they see on their screens everyday. Such is the influence of cosmetic surgery on social media that a study done by Dorman et al (2018, p334) found that in just one day in 2017 the hashtag #plasticsurgery had 523,361 posts associated with it while 7 other cosmetic surgery related hashtags were featured in over 100,000 posts each as well.
Unfortunately the most concerning part of the popularity cosmetic surgery has on social media is that the majority of users who want to modify their bodies use social media as a tool to research and educate themselves on plastic surgery on websites where majority of the posts relating to cosmetic surgery have very little educational value and are made by unqualified surgeons simply as advertisements which can lead to dangerous consequences for the consumer who wants to be come as ‘pretty’ as possible while spending the least amount of money. (Dorman et al, 2018)
References:
Dorfman, RG, Vaca, EE, Mahmood, E, Fine, NA & Schierle, CF 2018, ‘Plastic Surgery-Related Hashtag Utilization on Instagram: Implications for Education and Marketing’,Aesthetic Surgery Journal, vol. 38, no. 3, pp. 332–338, viewed 21 May 2022, <https://academic.oup.com/asj/article/38/3/332/4084591>.
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… A forma, a linha das versões definitivas, o aspecto sempre movediço da linguagem comum que encontramos no ensaio e na escolha que fazemos pela música quando ela nos invade e permanece em nós, é outra coisa …
Rilke/Pasternak/Tsvétaïeva
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b3nc0 · 3 years
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Demon of the Underground updated!
Demon of the Underground est paru!
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nusumigaki · 3 years
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私たちは、見ず知らずの相手の行動についての文脈の大切さを理解しようとしない。
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zhuhongs · 3 years
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not to be an anti work commie but the pjrase "sorry i overslept" is the SADDEST fucking phrase common in society. like dont apologize.. u needed to aleep. IM SORRY u didnt get the sleep u needed bc of whatever thing u had to be at
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chemwhat · 4 days
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N-METHYL-4-(P-FORMYLSTYRYL)PYRIDINIUM METHYLSULFATE CAS#: 74401-04-0
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IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product NameN-METHYL-4-(P-FORMYLSTYRYL)PYRIDINIUM METHYLSULFATE CAS#: 74401-04-0IUPAC Name4-benzaldehyde;methyl sulfateMolecular StructureCAS Registry Number 74401-04-0EINECS Number418-240-3Synonymsn-methyl-4-(p-formylstyryl)pyridinium methylsulfate74401-04-0EC 418-240-34-benzaldehyde;methyl sulfateSCHEMBL20298611HQMZBKRNRWIDME-SQQVDAMQSA-M4-(4-Formylstyryl)-1-methylpyridin-1-ium methyl sulfateMolecular FormulaC16H17NO5S Molecular Weight335.4InChIInChI=1S/C15H14NO.CH4O4S/c1-16-10-8-14(9-11-16)3-2-13-4-6-15(12-17)7-5-13;1-5-6(2,3)4/h2-12H,1H3;1H3,(H,2,3,4)/q+1;/p-1/b3-2+;InChI KeyHQMZBKRNRWIDME-SQQVDAMQSA-MIsomeric SMILESC1=CC=C(C=C1)/C=C/C2=CC=C(C=C2)C=O.COS(=O)(=O) Physical Data AppearanceLight yellow to yellow powder Melting Point, °C 226 - 228226 - 227225 - 226 Spectra Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Temperature (NMR Spectroscopy), °C Frequency (NMR Spectroscopy), MHzSpectrum1Hheavy water25400 Description (IR Spectroscopy)ATR (attenuated total reflectance), Bands, Spectrum Description (UV/VIS Spectroscopy)Solvent (UV/VIS Spectroscopy)Absorption Maxima (UV/VIS), nmSpectrumwater340 Route of Synthesis (ROS) Route of Synthesis (ROS) of N-METHYL-4-(P-FORMYLSTYRYL)PYRIDINIUM METHYLSULFATE CAS 74401-04-0 ConditionsYieldWith piperidine In methanol for 6h; Time; Reflux;Experimental Procedure1.2 2) SBQ SynthesisReaction flask was added 20.7 g terephthalic aldehyde, 1.0 g of piperidine, methanol, 30mL, was added dropwise at reflux temperature of the intermediate solution was added dropwise to refluxing was continued for 6h, cooled to room temperature, filtered, the cake washed with 100mL ethyl acetate wash 2 or 3 times to give 15 g crude SBQ, the filtrate can be further recycled products, crude yield 63%.3) SBQ crude product was purifiedReactor SBQ crude 15 grams, 25 grams of methanol at 80 oil bath and stirred 0.5h, filtered, and the cake was discarded impurities, to the filtrate was added 6.7 grams of water, 0.45 g of acetic acid, at 50 to the whole solution, and then at -10 crystallization, filtration, and dried to give crystals 12 grams. The resulting crystals by UV, IR, NMR detection, in line with the target structure of the product.The crystal purity greater than 99% (Figure 1 and Table 1), melting range of 226 ~ 228 , with 4-methylpyridine count, pure product yield of 63%.12 g Safety and Hazards Pictogram(s)SignalWarningGHS Hazard StatementsH317 (100%): May cause an allergic skin reaction H412 (100%): Harmful to aquatic life with long lasting effects Precautionary Statement CodesP261, P272, P273, P280, P302+P352, P321, P333+P317, P362+P364, and P501(The corresponding statement to each P-code can be found at the GHS Classification page.) Other Data No data available DruglikenessLipinski rules componentMolecular Weight335.381logP2.945HBA5HBD0Matching Lipinski Rules4Veber rules componentPolar Surface Area (PSA)95.76Rotatable Bond (RotB)4Matching Veber Rules2 Use PatternN-Methyl-4-(p-formylstyryl)pyridinium methylsulfate is used as a composite material in water-soluble photosensitive coatings, primarily for producing photosensitive emulsions for screen printing. It outperforms binary diazonium powders, exhibiting high stability, no dark reactions, and excellent photosensitivity and thermal stability. A negative-working photosensitive agent used for esterifying pre-sensitized lithographic plates, it can substitute diazonium intermediates with superior quality, faster exposure times, and longer shelf life. Read the full article
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