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#ml 4.13
baifengxis · 9 months
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Lmaooo hi hello (as if we didnt talk 5seconds ago fgfggf)
5 Favorite Steroline kisses please
And 5 Favorite Buddie scenes fgfgggh
ksdjfksdjfdksfd I LOVE YOU <333
Sorry for the late reply skdkfdg and sorry for not replying to you right now lmao
Top 5 Steroline Kisses:
First Proposal Kiss - 8.02
First Kiss - 6.14
VENDING MACHINE KISS <3 - 6.17
Second Proposal Kiss - 8.14
That kiss after they make ML&N to undo the spell and they kiss dressed as angel&devil <3 - 7.04
Top 5 Buddie Scenes:
"Because, Evan..." - 4.14 (Is anyone even surprised this is number 1? ksdkfkdg)
Shooting Scene - 4.13 (& "are you hurt?" from 4.14, this entire sequence basically)
Fight at the Supermarket - 3.05 (SO MARRIED my gosh)
Buck breaks down Eddie's door "they're all dead..." - 5.13
Every single scene of Buck&Eddie&Chris being a family I'm not even sorry lmao
Thanks so much babe this was such a good excuse to rewatch scenes, I loved it lol
ASK ME MY TOP 5 ANYTHING
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gqresearch24 · 27 days
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Agriculture Sensors Market Outlook Report 2024-2030: Trends, Strategic Insights, and Growth Opportunities | GQ Research
The Agriculture Sensors market is set to witness remarkable growth, as indicated by recent market analysis conducted by GQ Research. In 2023, the global Agriculture Sensors market showcased a significant presence, boasting a valuation of US 1.65 Billion. This underscores the substantial demand for Agriculture Sensors technology and its widespread adoption across various industries.
Get Sample of this Report at https://gqresearch.com/request-sample/global-agriculture-sensors-market/
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Projected Growth: Projections suggest that the Agriculture Sensors market will continue its upward trajectory, with a projected value of US$ 4.13 Billion by 2030. This growth is expected to be driven by technological advancements, increasing consumer demand, and expanding application areas.
Compound Annual Growth Rate (CAGR): The forecast period anticipates a Compound Annual Growth Rate (CAGR) of 9.75 %, reflecting a steady and robust growth rate for the Agriculture Sensors market over the coming years.
Technology Adoption:
Increasing adoption of agriculture sensors for precision farming and data-driven decision-making.
Sensors deployed for soil monitoring, crop health assessment, weather forecasting, and livestock management.
Integration of Internet of Things (IoT) connectivity for real-time data collection and analysis.
Application Diversity:
Soil Sensors: Monitoring soil moisture, nutrient levels, and pH for optimized irrigation and fertilization.
Crop Sensors: Assessing plant health, growth rates, and stress levels to optimize cultivation practices.
Weather Sensors: Predicting weather patterns and environmental conditions to mitigate risks and optimize crop management.
Livestock Sensors: Monitoring animal health, behavior, and productivity for improved management and welfare.
Consumer Preferences:
Demand for cost-effective sensors with high accuracy and reliability.
Preference for easy-to-use and interoperable sensor systems compatible with existing farm equipment and software.
Emphasis on data security and privacy protection to safeguard sensitive agricultural information.
Desire for scalable solutions that can be tailored to specific farm sizes and crop types.
Technological Advancements:
Advancements in sensor miniaturization, power efficiency, and wireless communication for improved sensor deployment and scalability.
Development of multispectral and hyperspectral imaging sensors for detailed crop analysis and disease detection.
Integration of artificial intelligence (AI) and machine learning (ML) algorithms for predictive analytics and autonomous decision-making.
Market Competition:
Intense competition among sensor manufacturers, technology providers, and agricultural equipment companies.
Differentiation through innovation in sensor technology, data analytics, and software solutions.
Strategic partnerships and collaborations to offer integrated solutions and expand market presence.
Focus on providing value-added services such as agronomic consulting and farm management platforms.
Environmental Considerations:
Promotion of sustainable agriculture practices through optimized resource usage and reduced environmental impact.
Minimization of chemical inputs and water usage through precision farming techniques enabled by sensor technology.
Integration of sensor data with environmental monitoring systems to support biodiversity conservation and habitat preservation.
Compliance with environmental regulations and standards governing pesticide use, water quality, and soil conservation.
Regional Dynamics: Different regions may exhibit varying growth rates and adoption patterns influenced by factors such as consumer preferences, technological infrastructure and regulatory frameworks.
Key players in the industry include:
auroras Srl Cso Piera Cillario
Caipos GmbH
CropIn Technology Solutions Private Limited
CropX inc.
dol-sensors A/S
Glana Sensors AB
Libelium Comunicaciones Distribuidas S.L.
Monnit Corporation
pycno agriculture
Sensaphone.
The research report provides a comprehensive analysis of the Agriculture Sensors market, offering insights into current trends, market dynamics and future prospects. It explores key factors driving growth, challenges faced by the industry, and potential opportunities for market players.
For more information and to access a complimentary sample report, visit Link to Sample Report: https://gqresearch.com/request-sample/global-agriculture-sensors-market/
 About GQ Research:
GQ Research is a company that is creating cutting edge, futuristic and informative reports in many different areas. Some of the most common areas where we generate reports are industry reports, country reports, company reports and everything in between.
Contact:
Jessica Joyal
+1 (614) 602 2897 | +919284395731 Website - https://gqresearch.com/
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christophe76460 · 9 months
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DIEU, LA SAINTE TRINITÉ (CONFESSION DE FOI DE WESTMINSTER)
Il n’est qu’un seul (Dt 4; 1 Co 8.4,6), vivant et vrai Dieu (1 Th 1.9; Jr 10.10), infini en son être et en sa perfection (Jb 11.7-9; 26.14), très pur esprit (Jn 4.24), invisible (1 Tm 1.17), incorporel, indivisible (Dt 4.15,16; Jn 4.24; Lc 24.39), impassible (Ac 14.11,15), immuable (Jc 1.17; Ml 3.6), immense (1 R 8.27; Jr 23.23,24), éternel (Ps 90.2; 1 Tm 1.17), incompréhensible (Ps 145.3), tout-puissant (Gn 17.1; Ap 4.8), très sage (Rm 16.27), très saint (Es 6.3; Ap 4.8), très libre (Ps 115.3), absolu (Ex 3.14). Il fait concourir toutes choses au conseil de sa propre volonté immuable et juste (Ep 1.11), pour sa propre gloire (Pr 16.4; Rm 11.36). Il est amour (1 Jn 4.8,16), grâce, miséricorde et patience. Il abonde en bonté et en vérité. Il pardonne l’iniquité, la transgression et le péché (Ex 34.6,7). Il récompense ceux qui le cherchent assidûment (Hé 11.6). Il est aussi très juste et terrible en ses jugements (Né 9.32,33). Il hait le péché (Ps 5.5,6), et n’innocente d’aucune manière le coupable (Né 1.2,3; Ex 34.7).
Dieu possède en lui-même et par lui-même toute vie (Jn 5.26), gloire (Ac 7.2), bonté (Ps 119.68) et bonheur (1 Tm 6.15; Rm 9.5). Il se suffit parfaitement à lui-même et n’a besoin d’aucune des créatures qu’il a faites (Ac 24,25); il ne tire d’elles aucune gloire (Jb 22.2,3), mais il manifeste seulement sa propre gloire en, par, vers et sur elles. Il est l’unique origine de tout être; tout est de lui, par lui et pour lui (Rm 11.36). Il détient l’autorité souveraine sur toutes choses et accomplit par elles, pour elles et en elles tout ce qui lui plaît (Ap 4.11; 1 Tm 6.15; Dn 4.25,35). Tout est évident et clair à ses yeux (Hé 4.13). Sa connaissance est infinie, infaillible, et ne doit rien à ses créatures (Rm 11.33,34; Ps 147.5); aussi pour lui rien n’est-il contingent ou incertain (Ac 15.18; Ez 11.5). Toutes ses pensées, toutes ses oeuvres et tous ses commandements sont très saints (Ps 145.17; Rm 7.12). Les anges et les hommes ainsi que toute autre créature lui doivent adoration, service et obéissance en tout ce qu’il lui plaît d’exiger (Ap 5.12-14).
Dans l’unité divine, il est trois personnes d’une seule et même substance, puissance et éternité: Dieu le Père, Dieu le Fils et Dieu le Saint-Esprit (1 Jn 7; Mt 3.16,17; 28.19; 2 Co 13.14). Le Père n’est engendré par personne et ne procède de personne. Le Fils est éternellement engendré du Père (Jn 1.14,18). Le Saint-Esprit procède éternellement du Père et du Fils (Jn 15.26; Ga 4.6).
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joinrabbi6 · 2 years
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Top Best Sword Art Online Keychains for Bikes
It seems to be an adorable Shark bottle opener Sword Art Online Keychains , which offers you an alternate encounter while drinking brews, can be placed on Keyrings with keys together. The Keychain comprises top-quality zinc combination-treated steel, including electroplate and cleaning tech, extravagance, and toughness, and the appearance will not vanish. The best use of this key is that it opens bottles effortlessly, and is additionally a helpful keychain. We can say that it is one of the most mind-blowing keychains for men. The miniature USB-c connector empowers you all to interface your USB Type C telephone or tablet, including your ordinary miniature USB link, to accomplish charging, sync, and information move. (No OTG similarity), Zinc-Alloy Micro USB to Type-C Converter Connector with Sword Art Online Keychains . Information Syncing and Charging with Super High-Speed USB-3.0, Universal for MacBook Pro-15, 16, 17 MacBook-12inch, Chromebook Pixel, Nexus, OnePlus, Samsung, LG. This item has been expertly tried and examined to satisfy USB Type-C Guidelines. The Adapter incorporates a 56k Resistor that monitors your materials against uncommon degrees of current that pass the recommended amount. To Use the keyring plug a standard Micro-USB link into the female connector of this Adapter, then plug the male connector of the Adapter into your Type-C gadget port. You are then ready to utilize a standard divider or vehicle charger for charging, or you can decide to move or match up information from your Type-C gadget to a PC. This treated steel material guarantees that it goes on for quite a while. … Perfect move up to your old Measurer - Makes an incredible gift for those extreme to search for … Stainless Steel Silver Hip Flask + 4 shot glasses 25 ml + Funnel + Wine opener Bar Set The Sword Art Online Keychains is not difficult to convey and take your number one wine with you any place you go. This is by and large a hip cup, which empowers you to convey a drinkable that you like the most. The Keychain is ideally suited for moving your wine, similar to bourbon, vodka, etc. This is essentially indestructible and it worked without any joints, ensuring durable, sealed accomplishment. Dimensions(H x W) are: 10.5cm x 4cm/4.13″ x 1.57″ (Approx.). It is intense, convenient, and has a pin cap with Keychain. The screw-on cap is helpful. In any case, some consideration directions are followed so it very well may be utilized long is that you need to flush and dry completely. This Keychain is the ideal Budget Gift for your friends and family. Purchaser's Guide 1. Material Quality-This is the fundamental point that you should consider before purchasing Sword Art Online Keychains for your keys. The most normal stuff for these keychains is treated steel and composite cowhide for the important veils. The material for keychains is tempered steel, as it is hypoallergic and reasonable for everybody. 2. Subject and plan Thou you want to consider concerning whether you want to arrange up a keychain of easygoing keyrings that make your eye or on the other hand assuming you will pick a specific topic, before-referenced as countries of the world, or a sort of creature that you could like, for instance, canines, felines or ponies or we can say that to have in your Keychain like wonder, dc universe, and so on. 3. Have a spending plan at the top of the priority list That is exceptionally gainful assuming you are wanting to get your picked Keychain following about so you can have an assessment of how much interest you wish to make. The Keychain you need is significantly more than others than you should consider because Keychain is only simply used to hold keys, so you should consider your financial plan before getting it. 4. Sturdiness The best keychains are tough and strong. If you have any desire to purchase a keychain, then you should consider its solidarity. You should search for the Keychain that will keep going long. Furthermore, all of you can decide the sturdiness of a keychain by perusing the audits of the item and conversing with your companions if he/she got that one. Individuals commonly accept keyrings as gifts. Such you could see that you already own a less as well if you haven't deliberately spilled out and bought one. Investigates the keyring you accomplish every day express anything about your conversance of style and character? Why not get some downtime to get yourself a new keyring that you like? Whether you are searching for one that is put together with metal, plastic, elastic, wood, cowhide, or even precious stone, we make certain there is a keyring out there to suit your requirements. so all of you should purchase keychains with the goal that your keys are protected. You have all the admittance to them.
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cartsilver1 · 2 years
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Top Best Sword Art Online Keychains for Bikes
It seems to be an adorable Shark bottle opener Sword Art Online Keychains , which offers you an alternate encounter while drinking brews, can be placed on Keyrings with keys together. The Keychain comprises top-quality zinc combination-treated steel, including electroplate and cleaning tech, extravagance, and toughness, and the appearance will not vanish. The best use of this key is that it opens bottles effortlessly, and is additionally a helpful keychain. We can say that it is one of the most mind-blowing keychains for men. The miniature USB-c connector empowers you all to interface your USB Type C telephone or tablet, including your ordinary miniature USB link, to accomplish charging, sync, and information move. (No OTG similarity), Zinc-Alloy Micro USB to Type-C Converter Connector with Sword Art Online Keychains. Information Syncing and Charging with Super High-Speed USB-3.0, Universal for MacBook Pro-15, 16, 17 MacBook-12inch, Chromebook Pixel, Nexus, OnePlus, Samsung, LG. This item has been expertly tried and examined to satisfy USB Type-C Guidelines. The Adapter incorporates a 56k Resistor that monitors your materials against uncommon degrees of current that pass the recommended amount. To Use the keyring plug a standard Micro-USB link into the female connector of this Adapter, then plug the male connector of the Adapter into your Type-C gadget port. You are then ready to utilize a standard divider or vehicle charger for charging, or you can decide to move or match up information from your Type-C gadget to a PC. This treated steel material guarantees that it goes on for quite a while. … Perfect move up to your old Measurer - Makes an incredible gift for those extreme to search for … Stainless Steel Silver Hip Flask + 4 shot glasses 25 ml + Funnel + Wine opener Bar Set The Sword Art Online Keychains is not difficult to convey and take your number one wine with you any place you go. This is by and large a hip cup, which empowers you to convey a drinkable that you like the most. The Keychain is ideally suited for moving your wine, similar to bourbon, vodka, etc. This is essentially indestructible and it worked without any joints, ensuring durable, sealed accomplishment. Dimensions(H x W) are: 10.5cm x 4cm/4.13″ x 1.57″ (Approx.). It is intense, convenient, and has a pin cap with Keychain. The screw-on cap is helpful. In any case, some consideration directions are followed so it very well may be utilized long is that you need to flush and dry completely. This Keychain is the ideal Budget Gift for your friends and family. Purchaser's Guide 1. Material Quality-This is the fundamental point that you should consider before purchasing Sword Art Online Keychains for your keys. The most normal stuff for these keychains is treated steel and composite cowhide for the important veils. The material for keychains is tempered steel, as it is hypoallergic and reasonable for everybody. 2. Subject and plan Thou you want to consider concerning whether you want to arrange up a keychain of easygoing keyrings that make your eye or on the other hand assuming you will pick a specific topic, before-referenced as countries of the world, or a sort of creature that you could like, for instance, canines, felines or ponies or we can say that to have in your Keychain like wonder, dc universe, and so on. 3. Have a spending plan at the top of the priority list That is exceptionally gainful assuming you are wanting to get your picked Keychain following about so you can have an assessment of how much interest you wish to make. The Keychain you need is significantly more than others than you should consider because Keychain is only simply used to hold keys, so you should consider your financial plan before getting it. 4. Sturdiness The best keychains are tough and strong. If you have any desire to purchase a keychain, then you should consider its solidarity. You should search for the Keychain that will keep going long. Furthermore, all of you can decide the sturdiness of a keychain by perusing the audits of the item and conversing with your companions if he/she got that one. Individuals commonly accept keyrings as gifts. Such you could see that you already own a less as well if you haven't deliberately spilled out and bought one. Investigates the keyring you accomplish every day express anything about your conversance of style and character? Why not get some downtime to get yourself a new keyring that you like? Whether https://animekeychains.com/collections/sword-art-online-keychains/ are searching for one that is put together with metal, plastic, elastic, wood, cowhide, or even precious stone, we make certain there is a keyring out there to suit your requirements. so all of you should purchase keychains with the goal that your keys are protected. You have all the admittance to them.
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the-bluespirit · 3 years
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Minor earthquake, 3 mag has occurred near Circleville in Utah
Earthquake News on http://www.earthquakenewstoday.com/2020/10/03/minor-earthquake-3-mag-has-occurred-near-circleville-in-utah-2/
Minor earthquake, 3 mag has occurred near Circleville in Utah
A minor earthquake with magnitude 3 (ml/mb) was detected on Saturday near Cedar City, Enoch, United States. The temblor was picked up at 13:41:46/1:41 pm (UTC/GMT) at a depth of 4.13 km (3 miles). Did you hear creaking or other noises?
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tomatodeals · 2 years
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Natural Vibes ~ Ayurvedic Vitamin C Skin Care Serum 30 ml ~ Reduces signs of ageing,
Natural Vibes ~ Ayurvedic Vitamin C Skin Care Serum 30 ml ~ Reduces signs of ageing,
Price: (as of – Details) Our serum will reduce signs of ageing and improve your skins complexion. It will also reduce acne, wrinkles, fine lines and help you maintain a healthy, radiant skin Product Dimensions ‏ : ‎ 2.36 x 2.36 x 4.13 inches; 3.53 Ounces Manufacturer ‏ : ‎ Natural Vibes ASIN ‏ : ‎ B08R3L2V68 ☘️Our serum will reduce signs of ageing and improve your skin complexion. It will also…
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christophe76460 · 3 years
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LA TRINITÉ
Par. 1 – Le Seigneur notre Dieu est le seul Dieu vrai et vivant. Il existe en lui‑même et de lui-même, infini en son être et sa perfection. Son essence ne peut être comprise par nul autre que lui‑même; il est esprit très pur, invisible, incorporel, indivisible, impassible. Lui seul est immortel et habite une lumière inaccessible aux hommes; il est immuable, immense, éternel, incompréhensible, tout‑puissant, infini à tous égards, très saint, très sage, très libre, absolu. Il opère toutes choses selon le conseil de sa propre volonté immuable et très juste, pour sa propre gloire. Il est amour, plein de grâce, de miséricorde et de patience. Il abonde en bonté et en vérité. Il pardonne l’iniquité, la transgression et le péché. Il récompense ceux qui le cherchent avec assiduité. Il est en outre très juste et terrible en ses jugements, haïssant tout péché et n’innocente d’aucune façon le coupable.
1. 1 Co 8.4, 6 ; Dt 6.4 2. Jr 10.10 ; Es 48.12 3. Ex 3.14 4. Jn 4.24
5. 1 Tm 1.17 ; Dt 4.15-16 6. Ml 3.6 7. 1 R 8.27 ; Jr 23.23 8. Ps 90.2
9. Gn 17.1 10. Es 6.3 11. Ps 115.3 ; Es 46.10 12. Pr 16.4 ; Rm 11.36
13. Ex 34.6-7 ; Hé 11.6 14. Né 9.32-33 15. Ps 5.5-6 16. Ex 34.7 ; Na 1.2-3
Par. 2 – Possédant toute vie, gloire, bonté et bonheur en lui‑même et de lui‑même, seul Dieu se suffit à lui‑même et par lui‑même, sans avoir besoin d’aucune créature qu’il a faite. Il ne dérive aucune gloire d’elles mais seulement manifeste sa gloire en, par, à et sur elles. Il est la seule source de tout être, de qui, par qui et pour qui toutes choses existent. Il possède une souveraineté absolue sur toutes les créatures, pour accomplir par elles, pour elles, et sur elles tout ce qui lui plaît. Tout se trouve manifeste et clair devant ses yeux. Sa connaissance est infinie, infaillible, et indépendante de la créature, de sorte que pour lui, rien n’est contingent ou incertain. Dans tous ses desseins, dans toutes ses œuvres, dans tous ses commandements, il est très saint. Les anges et les hommes sont tenus de lui rendre l’adoration et le culte qu’ils lui doivent comme créatures à leur Créateur, et tout ce qui lui plaît d’exiger d’eux en plus.
17. Jn 5.26 18. Ps 148.13 19. Ps 119.68 20. Jb 22.2-3 21. Rm 11.34-36
22. Dn 4.25, 34-35 23. Hé 4.13 24. Ez 11.5 ; Ac 15.18 25. Ps 145.17
26. Ap 5.12-14
Par. 3 – Dans cet Être divin et infini, il est trois subsistances, le Père, la Parole ou le Fils, et l’Esprit Saint, qui sont d’une seule substance, puissance et éternité. Chacun possède toute l’essence divine, et cependant l’essence n’est pas divisée. Le Père n’est engendré par personne, et il ne procède de personne; le Fils est éternellement engendré du Père, l’Esprit Saint procède du Père et du Fils. Les trois sont infinis, sans commencement, mais sont un seul Dieu, qui ne doit pas être divisé selon la nature ou l’être, mais distingué selon les propriétés particulières qui se révèlent dans leurs relations personnelles mutuelles. La doctrine de la Trinité est le fondement de toute notre communion avec Dieu et de notre dépendance, source de réconfort, de lui.
27. 1 Jn 5.7 ; Mt 28.19 ; 2 Co 13.14 28. Ex 3.14 ; Jn 14.11 ; 1 Co 8.6
29. Jn 1.14, 18 30. Jn 15.26 ; Ga 4.6
Source: Confession de Foi de Westminster de 1689
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gardennero · 3 years
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$93.04 31% off sell - Pinlo High Speed Blender Mini Portable Juicer Fruit Vegetable Mixer Meat Grinder Food Processor - White - 5A36665612 Description:With mini size and lightweight body and portable and exquisite design, the Pinlo Little Monster Fruit and Vegetable Machine has 500W / 30000RPM tough and powerful electric motor and eddy-current stirring system, providing you tasty juice rapidly and great using experience.Features:- Mini size and adorable body: simple and exquisite design, providing you great viewing feeling- 500W / 30000RPM electric motor: tough and powerful, helping you smash the fruit or ice quickly- Chain press structure: easy for you to operate, simple and safe- Strong system: equipped with eddy-current stirring system, the machine provides you tasty juice rapidly- External whorl design: you can clean it thoroughly, no need to worry the remains, convenient and safeSpecifications:Rated power: 500WRated voltage: 220VCapacity: 450mlNote:When cooking fruits or vegetables, cut them into blocks, making them more delicate.It is not recommended that this product be used to crush hard food materials such as sugar, nuts, medicinal materials, etc.Don't cook overheated food (the highest temperature is 40 Deg.C). Don't add boiled water to avoid scalding.When cleaning the silicone rubber ring of the machine, be careful not to touch the edge of the knife, so as not to cut the sealing ring.When cooking, do not add more than 450 ml of processing capacity indicated on the cooking cup.The working time of dry cooking materials should not exceed 30 seconds.The working time of liquid cooking should not exceed 1 minute, and the interval between two consecutive uses should be at least 1 minute.It is strictly forbidden to idle the cooking cup for a long time (no food in the cup) or to use it under overload. 1.500 Product size: 35.00 x 10.50 x 10.50 cm / 13.78 x 4.13 x 4.13 inches Package weight: 1.904 kg Package size: 36.00 x 11.00 x 11.00 cm / 14.17 x 4.33 x 4.33 inches Package Contents: 1 x Blender, 1 x Lid more product select from our Kitchen Appliances:https://www.gardennero.com/1215-kitchen-appliances #& # # # #
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reflexoesbiblicas · 3 years
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O TABERNÁCULO
INTRODUÇÃO
_ O Tabernáculo foi o mais que perfeito projeto do Criador, sua maior Glória já vista pelo homem. Deus, por meio do tabernáculo, fez-se conhecer o único caminho que leva a reconciliação ao homem. O tabernáculo revelou a Santidade de Yahweh e a Glória de Yeshua (Ex 34.10).
_ Yahweh ordenou a Moises que construísse um tabernáculo (Ex 25.1-9), o qual era uma simples representação do verdadeiro tabernáculo celestial (Hb 9.23-24); ele era formado por um santuário, uma tenda móvel, que possuía dois compartimentos, nomeados por “Lugar Santo” e “Lugar Santíssimo” (Hb 9.1-5); a tenda ficava no interior de um pátio, o qual era cercado por cortinas fixadas em colunas.  
_ O tabernáculo estava repleto de tipos, símbolos e rituais; possuía vários objetos destinados aos sacrifícios para expiação de pecados e para o ministério sacerdotal (Ex 40.1-8, 18-38).  
FIGURAS DE LINGUAGEM
_ Devemos conhecer as figuras de linguagem utilizadas na Bíblia para poder compreender seus textos e interpretar suas mensagens:  
TIPO:
Algo que tem por objetivo representar aquilo que é superior, o qual deve possuir a ideia ou a semelhança do que se quer representar. O tipo é a sombra que indica o que é real, é a foto do objeto, o qual é denominado por antítipo.  
ANTÍTIPO:
É o objeto que foi fotografado. É o cumprimento do Tipo. Exemplo:
a) O tabernáculo de Moises “tipo” (Ex 26.30), é a imagem do tabernáculo celestial “antítipo” (Hb 9.11, 24).
b) Jesus é o antítipo do tabernáculo de Moises. Jesus cumpriu, ou seja, consumou o propósito do tabernáculo (Jo 14.6).  
SÍMBOLO:
É um objeto real ou imaginário, ou ainda, uma ação ao qual se atribui um significado para representar em vez de afirmar as qualidades de outro elemento.  Exemplo:
a) Vinha é símbolo da nação de Israel (Mt 21.33).  
b) Água é símbolo do Espírito Santo (Jo 7.38-39).  
ALEGORIA:
É uma narrativa ou expressão que pode ou não ser verídica e contém muitos aspectos que simbolizam realidades espirituais.  Ex.: Agar (Gl 4.24-26).
PARÁBOLA:
É uma narrativa que contém uma comparação; a parábola possui um só elemento principal de comparação.  Exemplo: (Mt 13.44).
A PORTA  
_ A porta, ou cortina, (Ex 27.16) era o único acesso ao átrio, conseguinte, o único acesso ao caminho para o Lugar Santíssimo.  Apenas os sacerdotes poderiam permanecer no Átrio e no Lugar Santo, enquanto realizavam suas atividades e apenas o sumo sacerdote poderia entrar no Lugar Santíssimo e ali permanecer enquanto realizasse os rituais.
AS TRÊS PORTAS:
_ A porta era uma cortina de linho: havia uma cortina de acesso ao pátio (Ex 27.16); uma outra, a qual dava acesso ao Lugar Santo (Ex 26.36-37); e o Véu do Santuário, o qual dividia a tenda em duas partes e separava o Lugar Santíssimo do Lugar Santo (Ex 26.31-33).  
_ A porta era de linho fino e colorida (Ex 27.16): o linho representa a justiça de Cristo; o azul é a cor do céu e indica que o Salvador é celestial e divino (Jo 3.13); a púrpura “roxo” tipifica realeza e representa a glória celestial de Cristo, o Rei dos Reis (Jo 19.2-3; Ap 19.16); o carmesim “escarlate ou vermelho” representa o pecado (Ap 17.3-4, 6) e também o sangue de Cristo, o qual se fez pecado por nós (Is 1.18; 2Co 5.21).
_ A Porta é Yeshua (Jo 10.7-9); as três portas eram semelhantes, mas cada uma com um significado simbólico diferente: a cortina do Átrio representa o sacrifício de Cristo que resulta na justificação do homem (Tt 3.4-7), a cortina do Lugar Santo representa a ressurreição de Cristo e a nossa santificação (1Ts 4.1-7; 1Pe 3.21) e a cortina do Véu do Lugar Santíssimo representa a Glorificação de Cristo e a nossa eterna Salvação (Rm 8.16-17; Ap 19.1,7-8).
_ Reflexão:  Adão vivia na presença de Deus no jardim do Éden, porém após o pecado, Deus o expulsou e colocou Querubins para proteger o caminho, impedindo o homem de retornar à sua presença (Gn 3.24), por causa de seus pecados.  Entretanto, o próprio Yahweh revelou e disponibilizou uma porta de acesso ao caminho que conduz o homem de volta à sua presença, por meio do Tabernáculo (Jo 10.7; 14.6); este glorioso projeto foi consumado por Cristo no monte Gólgota (Jo 17.4; 19.28-30; Mc 15.37-39).  
O ÁTRIO
_ O átrio, ou pátio, era cercado por cortinas fixadas por colunas e possuía apenas uma entrada “a porta”; no interior do átrio encontrava-se o altar de holocausto, a bacia de bronze e a tenda (Ex 27.9-19; 40.6-8 ); após entrar pela porta do átrio, primeiramente se observava o altar, depois a bacia e a tenda; no interior da tenda o primeiro compartimento era o Lugar Santo e posteriormente o Lugar Santíssimo; o caminho entre a porta do átrio até o  Lugar Santíssimo, “local da presença de Deus”, só era possível ao sumo-sacerdote (Lv 16.17,29-33).      
AS CORTINAS:
_ As cortinas eram de linho fino e branco (Ex 27.9,18); o linho representa a justiça pessoal (Ap 19.6-8,14); as cortinas ao redor do átrio impediam o acesso ao seu interior, indicando que Deus requer uma vida justa e sem pecados, para poder se aproximar Dele.
AS COLUNAS:
_ A cortina que dá acesso ao Lugar Santo era sustentada por colunas; estas colunas eram de madeira e revestidas de ouro (Ex 26.37), com base de bronze; a madeira de acácia indicava a humanidade incorruptível de Jesus e o ouro a sua divindade; já o bronze, que é a base, é símbolo do fogo e indica juízo por meio do sacrifício, o qual purifica, (Ap 1.15; 2.18).
O ALTAR DO HOLOCAUSTO
_ Era uma mesa oca, revestida de cobre ou bronze, que tinha por cima uma grelha onde se colocava o animal sacrificado para ser queimado (Ex 27.1-8; 40.6) no altar se realizava os sacrifícios de expiação de pecados; o ritual consistia em sacrificar um animal inocente no lugar do ofertante pecador, e se Deus aceitasse este sacrifício, os pecados cometidos pelo ofertante seriam perdoados (Lv 1.1-9; 4.27-31).
_ O altar de bronze ficava logo após a porta do átrio, antes da bacia de bronze; entrando pela porta do átrio era o primeiro objeto a ser visto, o “local de morte”; indicando que deveria haver sangue substitutivo, para que o sacerdote e ou o ofertante pudessem prosseguir (Lv 1.1-5).  
_ A imposição das mãos do ofertante sobre a cabeça do animal que seria sacrificado, simbolizava a conscientização do pecado, do arrependimento e da transferência da punição para o animal inocente, a “morte substitutiva” (Lv 1.2-5; 16.20-22).  
_ Yeshua entregou sua vida em nosso lugar (1Co 15.3; 2Co 5.14-15; 1Pe 3.18); após o sacrifício na Cruz no monte Gólgota, nenhum outro sacrifício para expiação de pecados é aceito por Deus (Hb 9.11-15; 10.1-5, 8-10).
_ O altar de bronze “tipo” e o sacrifício “tipo”, foram consumados na Cruz “antítipo” no monte Gólgota, com Jesus crucificado “antítipo” (Cl 2.13-14; Hb 10.1, 5, 9-10).
A BACIA DE BRONZE
_ Era uma vasilha que continha água para a lavagem dos pés e das mãos dos sacerdotes, um ritual de purificação exterior do corpo, para que pudessem entrar no Lugar Santo (Ex 30.17-21); os pés representam o andar e as mãos representam o agir, no Espírito (Jo 13.3-10).  
_ A água é usada para lavagem, para purificação, “tipo”; o Espírito Santo opera nos salvos a “lavagem da regeneração” (Tt 3.5), mediante a Palavra de Deus (Jo 15.3; Jo 17.17), simbolizada pela água (Ef 5.26); assim como a água estava na Bacia, o Espírito Santo está na Palavra de Deus.  
_ Yeshua nos oferece a água para a nossa purificação, conseguinte o acesso ao Lugar Santo (Jo 4.13-14; 7.37-39): o ritual para a purificação pela água, “tipo” (Ex 30.20), é consumado por meio do batismo com o Espírito Santo, “antítipo” (Ef 1.13-14; 2Co 1.21-22), realizado por Jesus Cristo (Ez 36.25-27; Jo 1.29-33), conseguinte, o acesso ao Reino de Deus (Jo 3.5; 1Jo 1.8-9; Hb 10.22).  
O LUGAR SANTO
_ O Lugar Santo era o primeiro compartimento da tenda do encontro, local onde se encontrava a mesa dos Pães, o Candelabro e o Altar de incenso (Ex 40.1-5).  
_ O Lugar Santo “tipo” representava o Reino de Deus “antítipo” (Mt 12.28; At 1.3; 28.23): lugar onde habita a Igreja de Cristo (Cl 1.13-14), ou seja, onde habita os nascidos de Deus (Jo 1.10-13; 3.5-8), ou ainda, onde habita os sacerdotes reais (1Pe 2.2-5, 9).  
O CANDELABRO
_ O mesmo que castiçal, candeeiro ou menorá, era um móvel construído de ouro maciço que continha sete lâmpadas, as quais forneciam luz para o Lugar Santo (Ex 25.31, 37; Lv 24.1-4).  
_ O ouro representa a divindade de Cristo; as sete lâmpadas representam os sete espíritos de Deus (Ap 4.5); a luz também é “tipo” da Palavra de Deus (Sl 119.105; 2Pe 1.19); e as lâmpadas precisavam do azeite para brilhar, assim como os salvos precisam do Espirito Santo para refletir com poder a Luz de Yeshua! (Sl 23.5; Mt 25.4).
_ O candelabro era um “tipo” de Cristo, aquele que é a luz para a Igreja (Jo 1.6-9; 8.12), aquele que ilumina o Reino de Deus.  
A MESA DOS PÃES DA PRESENÇA
_ Deus determinou que Moises construísse uma mesa de madeira e a revestisse de ouro; sobre a mesa seria colocado doze pães, denominados de pães da presença, pães asmos ou sagrados, os quais representavam o alimento espiritual para as doze tribos de Israel (Ex 25.23-24,30; Lv 24.5-8).
_ A Mesa da Proposição, também chamada Mesa do Senhor (Ml 1.12; 1Co 10.21) representa nossa participação na mesa do Senhor, nossa comunhão com Cristo (Lc 13.29; 1Jo 1.3-7).  
_ Os pães sagrados simbolizavam o conhecimento da palavra de Deus “tipo”, como também o alimento para a nação de Israel “tipo”; Yeshua Ha Mashiach, é a Palavra que se fez carne “antítipo” (Jo 1.1, 14; Cl 2.2-3), é o Pão da vida que alimenta a Igreja para a vida eterna (Jo 6.48-51; Cl 1.9-10; Ef 4.11-15).  
O ALTAR DO INCENSO
_ O Altar era uma mesa de madeira revestida de ouro; sobre a mesa o sumo sacerdote queimava incenso.  Deus aceitava apenas um tipo específico de incenso (Ex 30.34-38), este teria que ser queimado exclusivamente no Altar de ouro; o Altar se encontra no interior do Lugar Santo de frente ao Véu, que se encontra diante da Arca da Aliança (Ex 30.1-8).  
_ O incenso é “tipo” a as orações do povo de Deus é o “antítipo”; o altar representa o meio pelo qual estas orações chegam aos ouvidos de Deus; portanto, o altar de incenso tipifica as orações dos cristãos e a intercessão de Cristo (Rm 8.34; 1Tm 2.5; Hb 7.25), o grande sumo sacerdote (Hb 4.14-16; 9.11-12).
_ Deus não houve as orações daqueles que possuem pecados, ou seja, daqueles que não estão no interior do Lugar Santo “Reino de Deus” (Is 1.15-16; 59.2; Jo 9.31), mas aceita as orações daqueles que: reconhecem os seus pecados, se arrependem deles e buscam o perdão de Deus; que entram pela porta do átrio e oferecem a Deus o Cordeiro sem mancha e sem defeito (1Pe 1.17-20; 1Jo 2.1-2); estes recebem o Espírito de Cristo e são purificados pelo seu sangue (Rm 6.2-7; 8.1-2, 8-11; 1Jo 1.9); estes pedem em nome de Yeshua e recebem (Jo 14.13-14).
O INCENSO:
_ O incenso era santíssimo; possuía uma fragrância exclusiva e destinada somente a Deus (Ex 30.34-37) “tipo”; assim como as orações dos salvos devem ser destinadas única e exclusivamente a Deus, ou seja, ao Pai Celestial (Mt 6.6-9; 23.9; Jo 16.23-24); não podemos oferecer incenso santíssimo a intermediários (Ex 30.38).  
O VÉU
_ É uma cortina de tecido de linho fino, que separava o Lugar Santo do Lugar Santíssimo (Ex 26.31-35).  O véu simboliza a barreira de inimizade existente entre o homem e o seu Criador (Ef 2.11-18); o véu tipifica o corpo de Cristo (Hb 10.19-22).  
_ O véu do Santuário se rasgou de alto a baixo (Mt 27.50-51), o poder que rasgou o véu veio de cima! Deus removeu o véu, indicando que pela morte de seu Filho, figuradamente partido pelo meio, no pão (Lc.22.19), todas as exigências da justiça divina tinham sido satisfeitas e que agora o caminho à sua presença estava aberto.  
O LUGAR SANTÍSSIMO
_ É o segundo compartimento da tenda do encontro, também chamado de o “Santo dos Santos”; local onde se encontra a Arca da Aliança; neste local Deus se encontrava com Arão, ou seja, com o sumo sacerdote, uma vez por ano, no dia da expiação (Ex 40.1-5; 25.22; Lv 16.1-2, 29-34; Hb 9.3-4).  
_ O Lugar Santíssimo “Santo dos Santos”, simboliza a morada do Deus Altíssimo nos céus, o “Reino dos Céus” (Mt 8.11-12; 26.26-29).  
_Quando Yeshua voltar, Ele arrebatará a sua Igreja e a levará para o Reino dos Céus, entregando-a ao Pai Eterno (Mt 13.36-43; 1Co 15.20-24), para estar na presença de Yahweh por toda eternidade (Ap 11.18-19; 21.1-4, 22-23).  
A ARCA DA ALIANÇA
_ A arca foi construída de madeira de acácia e revestida de ouro; a tampa da arca era chamada de propiciatório e sobre ela foi construído dois querubins de ouro (Ex 25.10-22); no interior da arca encontrava-se o vaso de ouro contendo uma porção do maná, a vara de Arão que floresceu e as duas tabuas da aliança (Hb 9.3-5):
A VARA DE ARÃO:
_ Tratava-se do cajado de Arão que floresceu; simboliza a ressurreição de Yeshua e a ressurreição dos mortos (1Co 15.20-23).  
O MANÁ:
_ O maná foi o alimento fornecido por Deus ao seu povo durante a peregrinação no deserto, ele simboliza o alimento espiritual (Mt 4.4), e o fruto da arvore da vida (Ap 2.7).  
AS TABUAS DA ALIANÇA:
_ As tábuas continham a lei e os dez mandamentos (Ex 24.12; 32.15-19; 34.1); Deus desejava que o seu povo, gravassem suas leis em seus corações (Dt 6.4-8; Jr 31.31-33); no entanto foi Yeshua que as tinha no coração e que as cumpriu (Mt 5.17-18).
_ As duas tabuas, simbolizava a Aliança que Deus fez com Moises e com a nação de Israel (Ex 34.1,10); Yeshua é o ápice do cumprimento do Tabernáculo “tipo”, Ele veio como o grande Sumo Sacerdote e o mediador de uma nova Aliança, para que todos os que são chamados recebam a promessa da herança eterna (Hb 8.1-6, 13; 9.15).  
O PROPICIATÓRIO:
_ Era a tampa da Arca da Aliança, neste local o sumo sacerdote, aspergia o sangue para a propiciação pelos pecados (Lv 16.14, 32, 34); simbolizava o trono de Deus (Hb 9.11-12, 15, 23-24).  
OS QUERUBINS:
_ Os querubins de ouro, sobre o propiciatório, simbolizam os guardiões do trono de Yahweh (Gn 3.24; Is 37.16).  
SACERDÓCIO LEVÍTICO
_ Os sacerdotes eram os únicos que poderiam entrar pela porta do átrio e oferecer os sacrifícios a Deus.  O sumo sacerdote era o único que poderia adentrar no lugar santíssimo apenas uma vez por ano (Lv 16.1-2, 17, 32-34), indicando que através deste sacerdócio ninguém poderia permanecer na presença de Yahweh (Hb 9.1, 6-10).
_ O sistema sacerdotal levítico era “tipo” do Sacerdócio Real, o sacerdócio da Igreja “antítipo” (1Pe 2.4-9; Ap 1.5-6); os sacerdotes reais oferecem sacrifícios espirituais a Deus “ antítipo” (Hb 13.15-16; 1Pe 2.5) e não sacrifícios expiatórios “tipo”.
_ Yeshua, é o nosso sumo sacerdote (Hb 4.14-16) e através deste sacerdócio temos acesso ao lugar santíssimo (Hb 9.11-12; 10.19-22).  
REFLEXÃO PESSOAL:
O QUE COMPETE A NÓS FAZER DIANTE DO TABERNÁCULO?
_ Procurar, querer, entrar pela porta estreita (Mt 6.33; 7.13-14; Lc 13.24): Esta busca dá-se início quando cremos na existência do Criador e na sua soberania; quando reconhecemos que somos pecadores e dependentes do perdão e da misericórdia do Criador; quando reconhecemos que somos merecedores da morte eterna, ou seja, da separação definitiva da presença de Deus; quando reconhecemos que Yeshua, o Messias, é o único caminho (Jo 14.6) e decidimos aceita-lo como Senhor e Salvador de nossas vidas (Lc 2.11).  
Rener Luz  
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the-bluespirit · 3 years
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vsplusonline · 4 years
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LULAA Long Lasting Printed Eyebrow Powder with Brush
New Post has been published on https://apzweb.com/lulaa-long-lasting-printed-eyebrow-powder-with-brush/
LULAA Long Lasting Printed Eyebrow Powder with Brush
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Price: (as of Jan 01,1970 00:00:00 UTC – Details)
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Portable Long Lasting Printed Eyebrow Powder with BrushDescription:The printed eyebrow is designed for three different types and colors to meet your different needs. It is quick to use instead of blackening eyebrow for a long time.Features:- Long lasting and smudge-proof.- Three sorts of color and three types for your different needs.- Specially gentle and natural for makeup.- Convenient to carry in work days.- Suitable for all people and occasions.Methods:Pull out the sponge eyebrow firstly.Dip in eyebrow powder with a sponge eyebrow.Aim at the eyebrow and cover them directly on the eyebrow. Formulation: Powder Net weight(g/ml): 5 Waterproof / Water-Resistant: Yes Feature: Easy to Wear,Long-lasting,Natural,Waterproof / Water-Resistant 0.076 Package weight: 0.086 kg Product size (L x W x H): 7.20 x 4.30 x 4.00 cm / 2.83 x 1.69 x 1.57 inches Package size (L x W x H): 7.50 x 4.60 x 10.50 cm / 2.95 x 1.81 x 4.13 inches Package Content: 1 x Eyebrow Powder, 1 x Eyebrow Brush
Offers all-day flawless finish with oil control. Oil-free, fragrance-free, and won’t clog your pores Ideal for all types of cosmetics: perfect for liquids, powders or creams to produce a beautiful application of face and eye makeup. elegant wooden handle and ferrule handmade by a professional artist to ensure long-term use.
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choonskitchen-blog · 5 years
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Chicken, the most popular birds                    in the world
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                                                                 Photo retrieved from Reference.com
Chicken is the most popular birds in the world for its eggs and meat. Chickens that people are raising nowadays are believed to be originated from wild chickens in Myanmar, Malaysia, and India that were domesticated more than 3,000-4,000 years ago. Birds naturally grow fast, as migratory birds need to have fat reserves and be able to fly thousands of miles by September. Even if they hatch in late spring, they need to migrate south before winter comes. Although chickens are not migratory birds, they still grow faster than other livestock. Free-range organic chickens will reach its full size around 22 weeks after hatching. Two months from egg to processing plants is enough for selectively raised chickens. One chicken lays between 100 and 200 eggs a year. Also, chicken contains rich nutrients such as high-quality protein, fat, and mucin, which helps growing muscles, and has different flavors for different parts. Chickens are cooked in many ways. It is not expensive and has the advantage of being easy to buy anywhere. Moreover, while some meat is taboo for religious and cultural reasons, chicken is released from these issues and is widely consumed around the world.
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                                                                                   Photo by Choon Kim
                • Breast: Soft in texture, low in fat
                • Leg quarter: hard-bodied and rich in essential amino acids.
                • Wing: Rich in protein and collagen
                • Feet: Rich in collagen
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                                                                                          Photo by Choon Kim
I am going to choose the chicken breast as the main ingredient for my cooking today. Chicken breast is a muscle that covers the chest. Each chicken has two breasts. The average weight of a chicken breast depends on size and breed of chicken, but the recommended serving size is 4-6 oz portions in the commercial kitchen. Chicken breast is the part of the chicken that contains the largest amount of meat without bones. So you can handle it easily when you cook it, and it is also very convenient to eat. Breast meat contains little fat and rich protein in it with low in calories, which helps in losing weight. In addition, it has a wide range of options for cooking methods. For this reason, I prefer using chicken breasts. However, you should be careful when you’re cooking it. Due to low fat, it easily hardens in texture when you overcook them, and chicken breasts are the most expensive chicken part to buy.
To save money, I bought a whole chicken. I’ll butcher it to take the breast from them, And with the remaining bones, we can make chicken broth. I can save my money compared to buying pre-cut meat.
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                                                                                            Photo by Choon Kim
Then, I’ll show you how to cut a whole chicken
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                                                                                          Photos by Choon Kim
1. Legs: Open up the leg, cut between the thigh and breast. Pull the drum   
               back and pop out that bone from the joint cut right down.
 2. Wings: Cut between body and wing
3. Chicken breast & Fillet: Separate the chicken breast along the side of the 
                                           bone in the middle of the breast.
4.Separate thighs and leg: Cut the middle joint between the thighs and legs.
5. Separate wing and wing tip: Cut the middle of the wings into two wings.
• I’ve got 2 pieces chicken breast = 0.69 LB, precut chicken breast = $ 9.49/LB,
0.69 x 9.49= $6.55
•Whole chicken = $ 5.99/LB, chicken breast 0.69 LB x 5.99= $ 4.13
•$ 6.55 - $ 4.13= $ 2.42 (save)
Chicken breast is ready for cooking. The biggest value of chicken breast is high protein and low fat. This is definitely a benefit for health. However at the same time because of the low-fat content, chicken breasted dishes are often dry and tuff. I will take a cooking method to coat them with bread crumbs so that the chicken breast can stay juicy. Soak them in milk for 20 minutes before cooking to tenderize the meat and remove the smell.
Ø  Cheese Chicken cutlet with Tomato Sauce.
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                                                                                           Photo by Choon Kim
Ingredients: Chicken Breast (2 pieces: 314 g), Milk (175 ml),
                     Mozzarella cheese (100g), Parmesan Cheese (100 g),
                     Flour(1/2 cup), Egg (2 pieces),  Panko (Bread Crumb1 cup),
                    Tomato Sauce(200 g), Canola Oil (250 ml), Basil for Garnish,
                    Salt & pepper to taste.
Cooking step
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                                                                                           Photos by Choon Kim
1.     Season chicken breast with salt and pepper.
2.     Slice the middle of the chicken breast, but not separated so that cheese  
         can be added.
3.     Fill the inside of the sliced breast with mozzarella cheese.
4.     Close the chicken so that the cheese doesn't escape.
5.     Coat them with flour, eggs, and bread crumbs in order.
6.     Fry the coated chicken breast in oil.
7.     Place tomato sauce in oven container
8.     Place fried chicken breasts on tomato sauce and cover them with tomato 
        sauce again
9.     Cover the top of the sauce with parmesan cheese and chopped basil
10. Bake in the oven. (180 ̊C, 20 min)
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11.     Serve.
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                                                                                           Photos by Choon Kim
 References
Berger, K. (2018, January 11). Interview by Quora
 Bjorkman, K. (2016, October 5). Interview by Quor
Drew, N. (2016, September 21). Interview by Quora
Joo, S. (2012, September 5). Professor Philo's 82 ways to cook meat. Retrieved May 20, 2019, from https://terms.naver.com/entry.nhn?docId=1711654&cid=48180&categoryId=48246 
Naver. (2011). Part of chicken. [Photograph]. Retrieved from http://www.naver.com/ - 
Referance.com(n.d). Where Do Chickens Live? [Photograph]. Retrieved from https://www.reference.com/pets-animals/chickens-live-4b3ff89261c4a867
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Light earthquake, 4.13 mag was detected near The Geysers in CA
Earthquake News on http://www.earthquakenewstoday.com/2020/03/25/light-earthquake-4-13-mag-was-detected-near-the-geysers-in-ca/
Light earthquake, 4.13 mag was detected near The Geysers in CA
A light earthquake with magnitude 4.13 (ml/mb) was reported near Santa Rosa, Vallejo, Fairfield, Vacaville, Napa, Petaluma, United States on Wednesday. The temblor was reported at 03:57:37/3:57 am (local time epicenter) at a depth of 2.07 km (1 miles). Did you hear creaking or other noises?
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chemwhat · 3 years
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2-Iodoacetamide CAS#: 144-48-9
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IdentificationPhysical DataSpectraRoute of Synthesis (ROS)Safety and HazardsOther Data Identification Product Name2-IodoacetamideIUPAC Name2-iodoacetamideMolecular StructureCAS Registry Number 144-48-9EINECS Number205-630-1MDL NumberMFCD00008028Beilstein Registry NumberNo data availableSynonymsiodacetamide, iodoacetamidMolecular FormulaC2H4INO Molecular Weight184.96InChIInChI=1S/C2H4INO/c3-1-2(4)5/h1H2,(H2,4,5)InChI KeyPGLTVOMIXTUURA-UHFFFAOYSA-NCanonical SMILESC(C(=N)O)I Patent InformationPatent IDTitlePublication DateUS2013/65913COMPOUNDS2013WO2013/115661NEW QUATERNARY AMMONIUM SALTS, METHOD FOR PREPARATION AND APPLICATIONS THEREOF2013EP2077261METHOD FOR PRODUCING SUCCINIMIDE COMPOUND2009EP1612204HYDRAZONE DERIVATIVE2006 Physical Data AppearanceWhite CrystallineSolubilityH2O: 0.5 M at 20 °C, clear, colorlessFlash Point88 ºCRefractive index1.5560 (estimate)SensitivityLight Sensitive Melting Point, °C Solvent (Melting Point) 92 - 94benzene93 - 94H2O93 - 94CHCl395H2O Description (Association (MCS))Solvent (Association (MCS))Temperature (Association (MCS)), °CPartner (Association (MCS))Further physical properties of the complexH2O251-prop-2-en-1-oneFurther physical properties of the complexbovine serum albuminFurther physical properties of the complexH2O-196.1 - -123.1DNAFurther physical properties of the complexD2O, tetradeuteriomethanol-196.1 - -123.1DNA Spectra Description (NMR Spectroscopy)Nucleus (NMR Spectroscopy)Solvents (NMR Spectroscopy)Frequency (NMR Spectroscopy), MHzMAS (Magic-Angle Spinning), Chemical shifts, Spectrum13CChemical shifts13CCDCl3100.6 Description (IR Spectroscopy)Solvent (IR Spectroscopy)Comment (IR Spectroscopy)Bandssolid3520 - 425 cm**(-1)Bandsgas3520 - 425 cm**(-1)Bandsneat (no solvent)3520 - 425 cm**(-1)IR Description (Mass Spectrometry)gas chromatography mass spectrometry (GCMS), electron impact (EI), tandem mass spectrometry, spectrumelectrospray ionisation (ESI), spectrum Description (UV/VIS Spectroscopy)Solvent (UV/VIS Spectroscopy)Comment (UV/VIS Spectroscopy)Absorption Maxima (UV/VIS), nmExt./Abs. Coefficient, l·mol-1cm-1SpectrumH2O220 - 280 nmSpectrum230 - 300 nm Route of Synthesis (ROS) Route of Synthesis (ROS) of 2-Iodoacetamide CAS 144-48-9 ConditionsYieldWith sodium hydride In N,N-dimethyl-formamide at 70℃; for 8h;Experimental Procedure1 Example 1: N-(2,6-Dimethoxypyridin-3-yl)-N-(acetamido-2-yl)-9-methyl-3-carbazolesulfonamide (1)Preparation of N-(2,6-dimethoxypyridin-3-yl)-9-methyl-3-carbazolesulfonamide (IMB105) according toMitsumori, Susuμ Tsuri, Tatsuo; Honma, Tsunetoshi et al.The method of Journal of Medicinal Chemistry (2003), 46(12), 2436-2445 was synthesized.Dissolve N-(2,6-dimethoxypyridin-3-yl)-9-methyl-3-carbazolesulfonamide (IMB105) (0.30 g, 0.78 mmol) in 5 mL of dry DMF.Iodoacetamide (0.20 g, 1.1 mmol) and sodium hydride (40 mg, 60% in oil, 1.0 mmol) were added,The reaction was carried out at 70°C for 8 h. The reaction was complete by TLC.DMF was removed under reduced pressure, the residue was extracted with methylene chloride, and the water and saturated brine were washed sequentially and dried over anhydrous sodium sulfate.The mixture was filtered and purified by column chromatography on the filtrate (CDM/MeOH/concentrated aqueous ammonia = 40/1/0.1) to give 0.35 g of a solid (yield 98%).98%Stage #1: N-(2,6-dimethoxypyridine-3-yl)-9-methyl-9H-3-carbazole sulfonamide With sodium hydride In N,N-dimethyl-formamide; mineral oil for 0.5h; Inert atmosphere; Cooling with ice;Stage #2: iodacetamide In N,N-dimethyl-formamide; mineral oil at 70℃; for 12h; Inert atmosphere;Experimental Procedure4.1.6 2-((N-(2,6-dimethoxypyridin-3-yl)-9-methyl-9H-carbazole)-3-sulfonamido)acetamide (3q)IMB105 (310mg, 0.78mmol) was dissolved in dried DMF (5.0mL). The obtained solution was cooled on an ice-water bath. NaH (40mg, 1.0mmol, 60% in oil) was added to the solution, and the reaction mixture was stirred for 30min. Then 2-iodoacetamide (202mg, 1.1mmol) was added and the mixture was allowed to warm to 70°C and stirred for 12h. The solvent was removed in vacuo, and the obtained residue was extracted into ethyl acetate (100mL). The organic layer was washed consecutively with water (50mL), brine (50mL), dried over MgSO4, filtered, and concentrated in vacuo. The residue was purified on silica gel using dichloromethane/methanol (20:1) to afford 350mg (98%) of 3q as a white solid. 1HNMR (CDCl3, 400MHz) δ ppm 3.68 (3H, s), 3.89 (3H, s), 3.92 (3H, s), 4.13 (2H, m), 6.25 (1H, d, J=8.4Hz), 7.15 (1H, d, J=8.4Hz), 7.34 (1H, t, J=8.0Hz), 7.36 (1H, br s), 7.49 (1H, d, J=8.8Hz), 7.53 (1H, d, J=8.0Hz), 7.57 (1H, td, J=8.4, 1.6Hz), 7.76(1H, dd, J=8.4, 1.6Hz), 8.10 (1H, d, J=8.0Hz), 8.42 (1H, d, J=2.0Hz); 13CNMR (DMSO-d6, 100MHz) δ ppm 29.3, 51.9, 52.9, 53.5, 101.0, 109.1, 109.8, 114.3, 119.9, 120.4, 121.1, 124.7, 126.8, 129.0, 141.4, 142.5, 144.5, 158.3, 161.6, 169.6; HRMS (ESI+): m/z calcd for C22H23N4O5S +: 455.1377; found: 455.1384.98% Safety and Hazards Pictogram(s)SignalDangerGHS Hazard StatementsH301 (98.88%): Toxic if swallowed H317 (93.26%): May cause an allergic skin reaction H334 (88.76%): May cause allergy or asthma symptoms or breathing difficulties if inhaled H413 (66.29%): May cause long lasting harmful effects to aquatic life Information may vary between notifications depending on impurities, additives, and other factors. Precautionary Statement CodesP261, P264, P270, P272, P273, P280, P285, P301+P310, P302+P352, P304+P341, P321, P330, P333+P313, P342+P311, P363, P405, and P501(The corresponding statement to each P-code can be found at the GHS Classification page.) Other Data TransportationNot ClassifiedUnder the room temperature and away from lightHS Code292419StorageUnder the room temperature and away from lightShelf Life2 yearsMarket PriceUSD Use Pattern2-Iodoacetamide CAS#: 144-48-9 as Pharmaceuticals2-Iodoacetamide CAS#: 144-48-9 inhibiting virulence of A. baumannii bacteria in combination with an antibiotic2-Iodoacetamide CAS#: 144-48-9 inhibiting virulence of E. faecium bacteria in combination with an antibioticinhibiting virulence of Gram-negative bacteria in combination with an antibioticinhibiting virulence of Gram-positive bacteria in combination with an antibioticinhibiting virulence of K. pneumoniae bacteria in combination with an antibioticinhibiting virulence of P. aerugino bacteria in combination with an antibiotic Read the full article
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